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The electron-impact induced fragmentation of substituted 4-styrylquinolines

✍ Scribed by H. Güsten; L. Klasinc; D. Stefanović

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
399 KB
Volume
7
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The fragmentation of 4‐styrylquinoline (I), 4‐(p‐nitrostyryl)‐quinoline (II), 4‐(p‐chlorostyryl)‐quinoline (III), 4‐(p‐hydroxystyryl)‐quinoline (IV), 4‐(p‐methoxystyryl)‐quinoline (V), 4‐(p‐dimethylaminostyryl)‐quinoline (VI) and 4‐(p‐cyanostyryl)‐quinoline (VII) under electron‐impact in the mass spectrometer is reported. The role and the influence of substituents on the fragmentation scheme is discussed. The loss of the substituents from the molecular ion is correlated with LCAOMO quantities.

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