The electron affinity of water and the structure of the hydrated electron
โ Scribed by R.E. Ballard
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 151 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
111~ ~lcctron affinity of u'a!cr has been obtained by 3 new method and a value of 1.3 eV is propord.
This value is consi~zcnt uith an ice-like structure for the hydrated electron in which four water molecules are disposed about a csntrol w.~tcr anion, there beins small (--IO") chsngcs from rhe ice structure vnluos of the angles between the dipole "la::-~nls, If a solution cf potassium fcrrocyanide is irradiated with light of energy exceeding a threshold value,
๐ SIMILAR VOLUMES
The electron affinities of the Ianthanides (La through Lu) are estimated by considering the energy variations associated with changes in the 4f orbital population. The ground-state electron affmities are all predicted to be within therange +O.S eV to -0.3 eV.
The electron dftities of rhe actinides (AC through Lr) are estimated by considering the energy variations associated with changes in the Sf orbital population. The ground-state electron affinities arc all predicted to be within the range +I.0 IO -0.3 ev.