✦ LIBER ✦

The electron affinities of Si2H2, Si2H3, and Si2H4

✍ Scribed by Josef Kalcher; Alexander F. Sax

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 264 KB
Volume: 192
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)85497-x

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✦ Synopsis

The three title compounds are found to form stable negatively charged states. Si2H2 exhibits two anion states (2A s and 2Bs) corresponding to adiabatic electron affinities (EAs) of 1.76 and 1.23 eV. Si2H3 has two stable anion states ( tA and 3A) associated with EAs of 2.20 and I. 17 eV. Disilene shows a remarkably high adiabatic EA of 1.03 eV, but this electron attachment energy is very sensitive to the out-of-plane bending of the molecule.

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