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The Electrolytic Reduction of Bicyclic α-Aminoketones. A New Method for the Synthesis of Medium Rings 1 Containing Nitrogen 2,3

✍ Scribed by Leonard, Nelson J.; Swann, Sherlock; Figueras, John

Book ID
126254817
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
704 KB
Volume
74
Category
Article
ISSN
0002-7863

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## Abstract The 1,2‐dihydro‐1,2‐diphosphinine decacarbonylditungsten complex **1** has been used as a synthetic equivalent of the corresponding 1,2‐dianion **2**. These two 1,2‐positions can be linked by a (CH~2~)~4~ bridge to yield a [4.4.0] bicyclic structure **6** whose identity has been confirm