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The electrochemistry of thiocarbonyl and selenocarbonyl iron octaethylporphyrins

✍ Scribed by Lawrence A. Bottomley; Jean-Noel Gorce

Book ID
108428078
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
818 KB
Volume
7
Category
Article
ISSN
0277-5387

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Exhaustive electro-oxidation of ZnOEP in the presence of pyridine and Et ~4~ NPF ~6~ affords in high yield the new tetracationic porphyrin in which the four meso protons of ZnOEP are replaced by four pyridinium groups linked via their nitrogens: [ Zn -5,10,15,20-tetrakis(N-pyridiniumyl)-2,3,7,8,12,1