The electrochemistry ofpolycrystalline silver in 1 mol kg-' KOH at tempera'tures between 295 K and 478 K has been studied using potentiostatic polarization. At potentials corresponding to silver dissolution and to the early stages of Ag,O formation, the transient current data at all the temperatures
The electrochemistry of silver in KOH solutions at elevated temperatures—I. thermodynamics
✍ Scribed by Bruce G. Pound; Digby D. Macdonald; John W. Tomlinson
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 763 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0013-4686
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The (~c impedance properties of silver in 1 mol kg-' KOH were studied under potentiostatic conditious over the temperature range 295-478 K. Measurements were obtained over the frequency range 0.5 Hz-5 kHz, and were analyzed in terms of equivalent circuits. It was shown that provision for surface rou
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Isopiestic results for SrCl2(aq) and BaCl2(aq) were obtained at T = 498 K and T = 523 K. As a check on previously reported results for MgCl2(aq) (from T = 383 K to T = 473 K), new isopiestic measurements were made over the temperature range from 383 K to 523 K. The new measurements are slightly diff