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The electrochemistry of a stable Zn isoporphyrin

✍ Scribed by W.Ronald Fawcett; Milan Fedurco; Kevin M. Smith; Hong Xie

Publisher
Elsevier
Year
1993
Tongue
English
Weight
374 KB
Volume
354
Category
Article
ISSN
1572-6657

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Exhaustive electro-oxidation of ZnOEP in the presence of pyridine and Et ~4~ NPF ~6~ affords in high yield the new tetracationic porphyrin in which the four meso protons of ZnOEP are replaced by four pyridinium groups linked via their nitrogens: [ Zn -5,10,15,20-tetrakis(N-pyridiniumyl)-2,3,7,8,12,1