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The electrochemical reduction of oxygen in sulpholane

✍ Scribed by C. Louis; R.L. Benoit

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
565 KB
Volume
18
Category
Article
ISSN
0013-4686

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✦ Synopsis

The electrochemical reduction of oxygen on mercury has been studied in sulpholane, a dipolar aprotic solvent, by polarography and cyclic voltammetry. The influences of the nature of the supporting electrolyte, the water concentration and the addition of phenol, a more powerful proton donor than water, have been studied. A reaction scheme is proposed. A simple electrochemical method for determining the oxygen content of sulpholane has heen developed.

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✍ B. Lovreček; M. Batinic; J. Čaja πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 English βš– 501 KB

The electrochemical reduction of the oxygen has been studied on graphite in alkaline solution. Current-potential data have been obtained by the voltammetry on the rotating disc electrode and potential-time data by the galvanostatic method on a stationary electrode. The residual current which appears