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The electrochemical reduction of diazanaphthalenes; a spectro-electrochemical investigation

✍ Scribed by J. H. Wolsink; A. Spaans; D. M. W. van den Ham; D. Feil

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
551 KB
Volume
101
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The electrochemical reduction of diazanaphthalenes in dimethylformamide at first‐ and second‐wave diffusion levels has been investigated by means of transmission spectro‐electrochemical methods. It has been found that the reaction of dianions with parent neutral molecules is an essential step in the reaction mechanism. Rate constants for all non‐electrochemical steps have been measured or estimated.

Independent estimations of diffusion and absorbance coefficients are presented, as well as some principles of digital simulation.

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