𝔖 Bobbio Scriptorium
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The Electrochemical Reduction of Benzene—First Direct Determination of the Reduction Potential

✍ Scribed by Dr. John Mortensen; Priv.-Doz. Dr. Jürgen Heinze


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
224 KB
Volume
23
Category
Article
ISSN
0044-8249

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✦ Synopsis


from the voltammogram using known criteria. The maximum current ratio i,,/i,, deviates from Unity and indicates the subsequent reaction on the time-scale of the measurements.


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The electrochemical reduction-Bamberger substitution of 2nitroanisole in 1 M H 2 SO 4 yields predominantly 2,5-dimethoxyaniline, not the expected 2,4-isomer. The selectivity was found to be acid-and solvent-dependent, with lower acidity and less polar solvents favoring the formation of 2,4-