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The electrochemical insertion of alkali metals in transition metal monoxides

✍ Scribed by J. Vondrák; J. Bludská; V.N. Belan; V.B. Lazarev; Yu.E. Bogatov


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
509 KB
Volume
35
Category
Article
ISSN
0013-4686

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✦ Synopsis


Electrochemical insertion of hthmm was observed m monoxides ScO, TlO, and VO The dlffuslon coefficient m ScO and T10 1s 10-'4-10-1' cm* s-l and m VO, it 1s l-3 orders of magmtude smaller No insertion of hthmm m NbO was observed Sodium does not enter these components at all


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The current response of an electrode which absorbs reactant on a potential step was computed by digital simulation and by Boltzmann substitution under assumption of diffusion coefficient being a linear function of concentration. The results were expressed as an correction factor [I in Sand equation