The efficiency of singlet oxygen generation by substituted naphthalenes in benzene. Evidence for the participation of charge-transfer interactions
✍ Scribed by D.J. McGarvey; P.G. Szekeres; F. Wilkinson
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 526 KB
- Volume
- 199
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
An inverse correlation between the rate constant for oxygen quenching of the triplet state .( k:) and the effkiency of singlet oxygen generation (S,) is established for a range of substituted naphthalenes in benzene. The participation of charge-transfer interactions are implicated on the basis that the only property which varies significantly with the substituent is the oxidation potential (Es) of the naphthalene derivative. Using published electrochemical data, correlations between S,, k: and the free energy change for charge transfer (AC=) have been found with values of S, and ki ranging from 0.34 to 0.75 and from 5.0~ lo9 to I .2 X lo9 M-' s-' for I-methoxynaphthalene and l-cyanonaphthalene, respectively.