The effects of primary structure on the degradation of poly(ɛ-caprolactone)/poly(l-lactide) block copolymers
✍ Scribed by Michael R. Lostocco; Catherine A. Murphy; J.A. Cameron; Samuel J. Huang
- Book ID
- 108400385
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 449 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0141-3910
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## Abstract **Summary:** A binary blend of poly (L‐lactide) (PLLA) and poly(__ε__‐caprolactone) (PCL) of composition 70:30 by weight was prepared using a twin screw miniextruder and investigated by differential scanning calorimetry (DSC), optical microscopy and scanning electron microscopy (SEM). T
## Abstract The crystallization behavior of poly(oxyethylene) (PEG)/poly(L‐lactide) (PLLA) block copolymers with PEG (number‐average molecular weights __M__~n~ = 1000–6000) contents ≦ 18,3 wt.‐% has been studied under different isothermal temperature and linear cooling conditions. A differential sc
## SYNOPSIS Blends of poly(L-lactide) (PLLA) and poly(e-caprolactone) (PCL) were prepared in a corotating twin screw miniextruder (40 rpm, 200"). It was attempted to prepare multiblock copolymers by allowing a controlled number of transesterification reactions. Various catalysts (n-Bu,SnOMe, Sn(Oc