The effects of hydrogen on the deformation and fracture of nickel-iron alloys
β Scribed by M.L Wayman; G.C Smith
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 654 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0001-6160
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β¦ Synopsis
Slow strain-rate tensile tests have been performed on hydrogen-charged f.c.c. nickel-iron alloys. The hydrogen embrittlement observed in pure nickel is suppressed by alloying with iron so that the deformation and fracture behaviour of alloys containing 50 and 60 % o f of hydrogen at levels in the order of 3 om3/100 g. iron is unaffected by the presence These and other results indicate that the hydrogen embrittlement of nickel and nickel-iron alloys is associated with the grain boundary precipitation of a hydride which decomposes during or after fracture. As nickel is alloyed with iron the tendency for hydride formation decreases and the hydrogen embrittlement is correspondingly reduced. INFLUENCE DE L'HYDROGENE SUR LA DEFORMATION ET LA RUPTURE DES ALLIAGES NICKEL-FER Des essais de traction a faible vitesse de deformation ont Bte effect&s sur des alliages c.f.c. de nickelfer charge en hyd:ogene. La fragilisation due ti l'hydrogene, observee dens le nickel pur, est supprimee par addition de fer de sorte que le comportement a la deformation et a la rupture des alliages contenant 50 et 60 % de fer n'est pas affect6 par la presence de 3 cmS/lOO g d'hydrogene. Cesresultats, ainsi que d'autres, montrent que la fragilisation du nickel et des alliages nickel-fer par l'hydrogene est associee a la precipitation aux joints de grains d'un hydrure qui se decompose au oours de la rupture ou apres la rupture. Quand le nickel est allie au fer, la tendance Q la formation de l'hydrure diminue, et par consequent la fragilisation par l'hydrogene diminue Bgalement. DER EINFLUB VON WASSERSTOFF AUF DIE VERFORMUNG UND DEN BRUCH VON NICKEL-EISEN-LEGIERUNGEN Wasserstoffdotierte kubisch-lliichenzentrierte Nickel-Eisen-Legierungen wurden bei kleinen Verformungsgcsohwindigkeiten verformt. Die in reinem Nickel beobachtete Versprodung durch Wasserstoff wird durch Zulegieren von Eisen unterdrtiokt, so da6 das Verformungs-und Bruchverhalten von Legierungen mit 50 und 60 % Eisengehalt durch Wasserstoffanteile bis zu 3 cos/lOO g nicht beein&_&, wird. Diese und andere Ergebnisse deuten darauf hin, da6 die Versprijdung von Nickel und Nickel-Eisen-Legierungen durch Wasserstoff mit der Ausscheidung eines Hydrids an Korngrenzen und dessen Zerfall wahrend oder nach dem Bruch zusammenhlingt. Wird dem Nickel Eisen zulegiert, so nimmt die Tendenz zur Hydridbildung und entsprechend such die Wasserstoff-VersprGdung ab.
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