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The effects of hydration and Na+-NH4+ ion exchange on the unit cell size of zeolite-Y

✍ Scribed by Paul O. Fritz; Jack H. Lunsford; Chia-Min Fu


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
325 KB
Volume
8
Category
Article
ISSN
0144-2449

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✦ Synopsis


In an attempt to clarify the effect of hydration on the unit cell (u.c.) size of zeolite-Y, the lattice parameter was monitored at various stages of hydration. The u.c. was found to increase upon dehydration from 24.66 A for the Na-Y starting material to 24.75 A for the fully dehydrated material. The u.c. size was also found to increase upon decreasing the sodium content, with a dramatic rise at the very low sodium levels (< 0.1 Na wt%).


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On the structures of X- and Y- type zeol
✍ Brian Beagley; John Dwyer; Nick P. Evmerides; Ayad I.F. Hawa; Talib K. Ibrahim πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 English βš– 765 KB

Compositionally similar samples of hydrated Na-X zeolite with 220-265 water molecules per unit cell are shown by X-ray diffraction methods to exhibit structural differences. Three samples, independently treated to maximize Na and H20 content, crystallographically resemble the samples studied by Brou