The Raman spectra of three ring vibrational modes and and the Fermi resonance of ethylene (m 5 , m 6 m 7 ) m 2 -2m 7 carbonate in the solvents TMOS, benzene, methanol and water were studied as a function of concentration at room temperature. The pure dilution e β ect in non-polar solvents, as expecte
The effects of fluid density on the rotational Raman spectrum of hydrogen dissolved in supercritical carbon dioxide
β Scribed by Steven M. Howdle; Viktor N. Bagratashvili
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 442 KB
- Volume
- 214
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The rotational Raman spectrum of hydrogen dissolved in supercritical carbon dioxide ( scC02) is investigated. As the pressure, and hence density of the solution is increased, the lines broaden dramatically. The line broadening is compared with that of the vibrational line Q, (I ) and possible explanations for the behaviour, related to solvent-solute interactions, are discussed.
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