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The Effects of Atropisomerism and Porphyrin Deformation on57Fe Shieldings in Superstructured Hemoprotein Models

✍ Scribed by Ioannis P. Gerothanassis; Charalampos G. Kalodimos; Geoffrey E. Hawkes; Peter Haycock


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
86 KB
Volume
131
Category
Article
ISSN
1090-7807

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✦ Synopsis


Fe NMR chemical shifts of superstructured heme model comtransferred under argon into the NMR tube via a stainless pounds have been found to be extremely sensitive to atropisomersteel tube. 13 CO (99.7% enriched in 13 C and 11.9% in 18 O) ism and deformation (ruffling) of the porphyrin geometry. ᭧ 1998 under atmospheric pressure was then introduced to the Academic Press 56

Fe(III) complex while natural abundance CO was intro-