The effect of the supporting electrolyte on the electroreduction of ethyl bromide
โ Scribed by Riccardo Galli; Franco Olivani
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 427 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0022-0728
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๐ SIMILAR VOLUMES
The adsorption and the changes in the interfacial composition of octanoic acid at the mercury/electrolyte interface was studied by measuring the differential capacitance at different concentrations of the supporting electrolyte, at various supporting electrolyte systems and at various temperatures.
It is known 1-4 that the Ni 2+ ion forms in CN-solutions the very stable complex, [Ni(CN)4] 2-, which is essentially the only complex present even at a total concentration of CN-lower than the stoichiometric value. Under chemical or electrochemical reduction, this complex gives [Ni2(CN)614which is