The effect of the spin packet lineshape on the saturation of inhomogeneous resonances
β Scribed by R Boscaino; F.M Gelardi
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 993 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-2364
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π SIMILAR VOLUMES
T, relaxation of one set of nuclei causes an extra-broadening and an apparent reduction of the spin-spin splitting in the NMR spectrum of another set of nuclei coupled to it. These effects are demonstrated by lime-shape calculations for first order multiplets of spin l/2 nuclei. It is shown that in
The equations of motion for the density matrix are manipulated in spherical tensor form to derive formulas for the lineshapes of saturation-broadened spectroscopic transitions for gas-phase molecules. The formulas, which include consideration of the spatial degeneracy, are given for both plane-polar
Two types of inhomogeneities for a dimer in a condensed medium are introduced. One, the correlated part, which does not underlie exchange narrowing caused by excitation transfer. and an unconelated part. The interplay of the correlation and exchange narrowing on linebroadening is analysed.