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The Effect of the Solvent on the Polarographic Reduction of Cations 1

โœ Scribed by Bruss, Douglas B.; De Vries, Thomas


Book ID
126334303
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
489 KB
Volume
78
Category
Article
ISSN
0002-7863

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Effect of protic solvents on the polarog
โœ Sachiko Sakura; Heung Lark Lee; Taitiro Fujinaga ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 295 KB

Sodium and lithium ions are not reduced at the dropping mercury electrode in hexamethylphosphoric triamide containing 0.05 mol dm-3 tetraethylammonium perchlorate while rubidium and caesium ions show diffusion controlled, l-electron reduction waves. Thereduction of potassium ion is partially kinetic