The effect of terminal groups on the kinetics of chemiluminescence in the oxidation of poly(ϵ-caprolactam)
✍ Scribed by L Matisová-Rychlá; B Lánská; J Rychlý; N.C Billingham
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 612 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0141-3910
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Adiabatic temperature rise has been recorded as a function of polymerization time to investigate an adiabatic copolymerization kinetics of 1-caprolactam (CL) in the presence of several activators, considering different initial copolymerization temperatures ranging from 130 to 160ЊC. The copolymeriza
A study of the effect of catalyst (base) concentration and N-acylcaprolactam cocatalyst size and substitution on the fast anionic polymerization of caprolactam indicated that a steric effect due to cocatslyst size exists, and perhaps an electronic effect due to cocatalyst substitution was noted. The
## Abstract The concentrations of the cyclic oligomers (__C__~__i__~; __i__ = 3, 4, 5, and 6) in the polymeric products of ε‐caprolactam were determined by high‐performance liquid chromatography. The equilibrium data on the oligomers were obtained as a function of the polymerization temperature and