The effect of temperature on the cationic isomerization polymerization of 3-methyl-1-butene and 3-chloro-3-methyl-l-butene
β Scribed by Kennedy, J. P. ;Squires, R. G.
- Book ID
- 105340139
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 517 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0449-2994
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π SIMILAR VOLUMES
## Abstract 3βMethylβ1βbutene was polymerized in the presence of a number of homogeneous metallocene catalysts (coβcatalyst methylalumoxane). Contrary to literature reports, it was found that even the simplest __C__~2~βsymmetric metallocenes promote the isotactic polymerization of this monomer with
The elimination kinetics of the title compounds were carried out in a static system over the temperature range of 290-330Β°C and pressure range of 29.5-124 torr. The reactions, carried out in seasoned vessels with ally1 bromide, obey first-order rate law, are homogeneous and unimolecular. The tempera