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The Effect of Substituents upon the Rates of Hydrolysis of Fluorinated Esters

โœ Scribed by Moffat, Arlo; Hunt, Herschel


Book ID
118057245
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
335 KB
Volume
79
Category
Article
ISSN
0002-7863

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The overall kinetic solvent isotope effects on the acid catalyzed hydrolysis of a series of 2-aryl-2-diazocarboxylic esters ArCN2COOCH3, and one 2-aryl-2-diazocarboxamide C6H5CH2CON (CH,), vary inversely with the reactivity of the substrate, between limits of 3.14 and 1.46. A linear Hammett plot for