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The effect of substituents on the reactivity of aniline with phosphate radical

✍ Scribed by P. Subramanian; J. Rajaram; V. Ramakrishnan; J.C. Kuriacose

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 347 KB
Volume: 44
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86165-2

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✦ Synopsis

The reaction between aromatic amines and phosphate radical has been investigated. The reaction is accelerated by electron-releasing substituents and retarded by electronwithdraw@ ;sj;;i;uents the PO4 x . 0+ pointing to an electrophilic attack by values corre ate the effect of substituents well. The pay 1 than that for CO37 r o value for PO4 v is more positive indicating higher reactivity of phosphate radical towards aromatic amines than the carbonate radical.

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