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The Effect of Structure on Reactivity in Semicarbazone Formation 1

โœ Scribed by Anderson, Bruce M.; Jencks, William P.

Book ID
120195607
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
598 KB
Volume
82
Category
Article
ISSN
0002-7863

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โœ M. Calzadilla; A. Malpica; T. Cordova ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 58 KB ๐Ÿ‘ 2 views

Second-order rate constants for substituted benzaldehyde oxime formation increase linearly with the activity of hydrated protons over the pH range ca 2-7. Under these conditions, first-order rate constants show saturation behavior with increasing hydroxylamine concentration, establishing carbinolami