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The effect of solvent short range order on the solvent sensitivity of merocy anine dyes

โœ Scribed by F.J. Kampas


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
389 KB
Volume
26
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


A theoly of solvent sensitivity is presented which uses the Kirkwood-Friihlich theory of polar liquids to describe short range order in the solvent. This yields a consistent description of hydrogen bonding and non-hydrogen bonding solvents.


๐Ÿ“œ SIMILAR VOLUMES


Theoretical treatment of solvent effects
โœ H. Kuhn; A. Schweig ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 350 KB

The dye molecule in a saturated hydrocarbon solvent (instead of the vacuum) is taken as reference state: the a-electrons of solute and solvent are treated as a continuous medium of dielectric constant E o = 2. The n-electrons of the solute are assumed to be immersed in this medium. Solvent shifts O:

The Effect of Solvent on Competing Hydro
โœ Charles W. Jefford; Shigeo Kohmoto ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 213 KB

## Abstract The rates of the competitive photoโ€sensitized oxygenation of 2โ€isobutylideneadamantane (**1**) and 2โ€propylideneโ€adamantane (**2**) with 1, 1โ€diโ€__t__โ€butylโ€2โ€methoxyethane (**3**) in various solvents were determined. The rates for **1** and **2** were independent of solvent, whereas th