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The effect of solvent on the visible and ultra-violet absorption spectrum of [Re(py)4O2]+

โœ Scribed by John H. Beard; R. Kent Murmann


Book ID
118906928
Publisher
Elsevier Science
Year
1968
Weight
356 KB
Volume
30
Category
Article
ISSN
0022-1902

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Studies on the rate of isotopic oxygen e
โœ Fred F. Kashani; R. Kent Murmann ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 479 KB ๐Ÿ‘ 1 views

The rate of oxygen exchange between truns-[Re(py),02]+ and solvent water in py-pyH' buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25"C, and [pyl = 0.10 M. The observed rate constant for ex