The Effect of Silane Coupling Agents on the Viscoelastic Properties of Rubber Biocomposites

✍ Scribed by Maya Jacob; Bejoy Francis; K. T. Varughese; Sabu Thomas

• Publisher: John Wiley and Sons
• Year: 2006
• Tongue: English
• Weight: 258 KB
• Volume: 291
• Category: Article
• ISSN: 1438-7492
• DOI: 10.1002/mame.200600171

✦ Synopsis

Abstract

Summary: This paper deals with the dynamic mechanical study of sisal/oil palm hybrid fiber reinforced natural rubber composites (at frequency 1 Hz) with reference to the role of silane coupling agents. Composites were prepared using sisal and oil palm fibers subjected to chemical modifications with different types of silane coupling agents. The silanes used were Silane F8261 [1,1,2,2‐perfluorooctyl triethoxy silane], Silane A1100 [γ‐aminopropyltriethoxy silane] and Silane A151 [vinyl triethoxy silane]. It was observed that for treated composites, storage modulus and loss modulus increased while the damping property was found to decrease. Maximum E' was exhibited by the composite prepared from fibers treated with silane F8261 and minimum by composites containing fibers treated with silane A151. This was attributed to the reduced moisture absorbing capacity of chemically modified fibers leading to improved wetting. This in turn produced a strong interfacial interface giving rise to a much stiffer composite with higher modulus. Surface characterization of treated and untreated sisal fibers by XPS showed the presence of numerous elements on the surface of the fiber. Scanning electron micrographs of tensile fracture surfaces of treated and untreated composites demonstrated better fiber–matrix bonding for the treated composites.

Scheme of interaction of silanes with cellulosic fibers.

magnified imageScheme of interaction of silanes with cellulosic fibers.