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The effect of second-sphere coordination of 18-crown-6 ether on electronic spectra and electrochemical properties of [Ru(NH3)5L](PF6)3 and [Ru(NH3)5L](PF6)2

✍ Scribed by Isao Ando; Hiroaki Fujimoto; Kazuto Nakayama; Kikujiro Ujimoto; Hirondo Kurihara

Book ID: 108428348
Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 278 KB
Volume: 10
Category: Article
ISSN: 0277-5387
DOI: 10.1016/s0277-5387(00)81381-9

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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__