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The effect of p—π conjugation on the barrier to pyramidal sulphur inversion in pentacarbonylchromium complexes of thioethers

✍ Scribed by Adam Gryff-Keller; Przemysław Szczeciński; Hanna Koziel


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
272 KB
Volume
26
Category
Article
ISSN
0749-1581

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## Abstract The barriers to rotation about the C(O)N bond for 13 α‐alkyl‐ and α‐halo‐substituted __N__‐theyl‐__N__‐methylamides were determined by ^1^H NMR spectroscopy at coalescence temperature. Plots of Gibbs free energy (Δ__G__°) and Gibbs energy of activation (Δ__G__‡) values against Charton'