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The effect of protecting groups of the nucleobase and the sugar moieties on the acidic hydrolysis of the glycosidic bond of 2-́deoxyadenosine: a kinet

✍ Scribed by Gerald Remaud; Xiao-Xiong Zhou; Jyoti Chattopadhyaya; Mikko Oivanen; Harri Lönnberg

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
656 KB
Volume
43
Category
Article
ISSN
0040-4020

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✦ Synopsis

6 -The rate constants

for the hydrolysis of several isubstituted 2'-deoxyadenosines were measured at different con--145.7 -15a.

📜 SIMILAR VOLUMES

The effect of metal ion complex formatio
The effect of metal ion complex formation on acidic depurination of 2′-deoxyadenosine and 2′-deoxyguanosine
✍ Jorma Arpalahti; Rainer Käppi; Jari Hovinen; Harri Lönnberg; Jyoti Chattopadhyay 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 590 KB

The substitution inert N7-(dien)Pt(II) complex of 2'-deoxyguanosine has been shown to undergo acidic depurination 200 times less readily than the uncomplexed nucleoside, whereas the corresponding Nl-and N7-complexes of 2'-deoxyadenosine are depurinated almost as rapidly as the nucleoside itself. The