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The effect of pressure on the crystal structure of [Gd(PhCOO)3(DMF)]n to 3.7 GPa and the transition to a second phase at 5.0 GPa

✍ Scribed by Parois, Pascal; Moggach, Stephen A.; Lennie, Alistair R.; Warren, John E.; Brechin, Euan K.; Murrie, Mark; Parsons, Simon


Book ID
115536994
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
497 KB
Volume
39
Category
Article
ISSN
1477-9226

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An __in situ__ X-ray powder diffraction study has shown the cubic modification of (NH~4~)~2~SiF~6~ (cryptohalite, space group __Fm__Β―3__m__) at 0.2–0.3 GPa to transform irreversibly into the trigonal bararite, space group __P__Β―3__m__1. The anisotropy of lattice strain in the high-pressure phase of