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The effect of polar head charge delocalization on micellar aggregation numbers of decylpyridinium salts

✍ Scribed by Paul T Jacobs; E.W Anacker


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
251 KB
Volume
44
Category
Article
ISSN
0021-9797

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The Effect of Polar Head Charge Delocali
✍ Paul D.T. Huibers; Paul T. Jacobs πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 English βš– 64 KB

The distribution of charge in an isomeric series of decylpyridinium bromide surfactants is calculated using the AM1 semiempirical quantum mechanical molecular model. The aggregation numbers of the surfactants are shown to increase with a decrease in the residual partial charge in the alkyl tails, su