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The Effect of pH on Sanguinarine Iminium Ion Form

โœ Scribed by Jones, R. R.; Harkrader, R. J.; Southard, G. L.

Book ID
120239620
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
200 KB
Volume
49
Category
Article
ISSN
0163-3864

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Theoretical studies on the iminium ion-f
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โœ Chang Kon Kim; In Young Lee; Chan Kyung Kim; Ikchoon Lee ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 89 KB

The iminium ion forming reactions of YC 6 H 4 NHCH 2 NH 3 (I) and the corresponding carbon analog, YC 6 H 4 CH 2 CH 2 NH 3 (II) were studied theoretically at the MP2/6-31G\*//RHF/6-31G\* level. The iminium ionforming reactions are favored mainly due to a large amount of electron donation (0.05-0.06e