The effect of nitrogen donors on the reactivity of copper(I) aryloxides: Synthesis of thioncarbonates
โ Scribed by N. Narasimhamurthy; A.G. Samuelson
- Book ID
- 104216460
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 216 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Copper coordination complexes of the neutral tetradentate nitrogenโcontaining ligands tris(3,5โdimethylpyrazolโ1โylmethyl)amine (L0N4) and tris(3,5โdiisopropylpyrazolโ1โylmethyl)amine (L1N4), namely the copper(II) chlorido complexes [Cu^II^(L0N4)Cl~2~] (1) and [Cu^II^(L1N4)Cl~2~] (2), t
Stabilization of the bis(ฮผ-oxo)dicopper(III) intermediate is achieved by using a bidentate N-donor ligand with pendent indole rings: N,N-bis[(3-indolyl)methyl]-N-[(2'-pyridyl)methyl]amine (BIP). The intermediate decomposes to give products arising from N-dealkylation and a product with a spiro ring