The effect of (NH4)2HPO4 and (NH4)2SO4 on the spontaneous ignition properties of Pinus halepensis pine needles
โ Scribed by S. Liodakis; D. Bakirtzis; E. Lois; D. Gakis
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 243 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0379-7112
No coin nor oath required. For personal study only.
โฆ Synopsis
The spontaneous ignitability of Pinus halepensis pine needles was evaluated. Fire points and times taken for irradiated fuels to be ignited were correlated, at given heat intensity, to the airflow around the specimen and the sample size. The tests showed that increase of the airflow rate above 1.5 l min ร1 increased considerably the fire point values and ignition delay times. On the contrary, the sample size in the range investigated (0.2-1.0 g) showed a negligible effect on the ignition properties. The influence of fire chemical retardants (NH 4 ) 2 HPO 4 (DAP) and (NH 4 ) 2 SO 4 (AS) on the ignitability characteristics was studied under various concentration levels. The data in this study showed that the presence of DAP and AS increases the fire point, as well as the time required for ignition, and this effect is pronounced at high concentration levels. However, at lower temperatures, i.e. below 5001C, flaming combustion appears sensitive to the AS quantity applied, whereas at high temperatures (i.e. above 6001C) the DAP concentration had a major influence on its flammability behavior. In addition the time of combustion was slightly extended, therefore, the energy release rate was reduced in the presence of fire retardants, particularly of AS. The purpose of this study was to quantify the fire extinguishing capabilities of (NH 4 ) 2 HPO 4 and (NH 4 ) 2 SO 4 , commonly used chemicals in forest fires, by comparing the ignition properties of samples, prior and after retardant loading.
๐ SIMILAR VOLUMES
Isotherms at 0, 10, and 253C of the H 2 O+(NH 4 ) 2 HPO 4 + (NH 4 ) 2 SO 4 ternary system have been established by conductivity measurements in the considered temperature range (0+253C). Tracing the polythermal diagram has allowed to determine the existence domains of the solid phases: (NH 4 ) 2 HPO
Ahstract ~ The mechanism for the anodic formation of peroxydisulfate ion on a Ti-supported IrO, electrode was investigated in mixed aqueous solutions of H,SO., (NH&SO4 and NH,F. Peroxydisulfate ion can be formed in higher yield at lower overpotential on the Ti-supported IrO, electrode. comoared with