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The effect of multivalent cation dopants on lithium manganese spinel cathodes

✍ Scribed by A. de Kock; E. Ferg; R.J. Gummow

Book ID
108454673
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
471 KB
Volume
70
Category
Article
ISSN
0378-7753

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✍ Siqi Shi; Chuying Ouyang; Ding-sheng Wang; Liquan Chen; Xuejie Huang πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 195 KB

The effect of the cation doping on the electronic structure of spinel LiM y Mn 22y O 4 (M ΒΌ Cr, Mn, Fe, Co and Ni) has been calculated by first-principles. Our calculation shows that new M-3d bands emerge in the density of states compared with that in LiMn 2 O 4 . Simultaneously, the new O-2p bands