The effect of Mo2C derived carbon pore size on the electrical double-layer characteristics in propylene carbonate-based electrolyte
✍ Scribed by J. Leis; M. Arulepp; M. Käärik; A. Perkson
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 705 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0008-6223
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✦ Synopsis
Carbide-derived carbon (CDC) was synthesised from molybdenum carbide by extracting Mo atoms in a high-temperature chlorine atmosphere. A systematic study of the influence of pore size on the electrical double layer (EDL) performance was carried out with carbons synthesised in the temperature interval of 500-900 °C. Strong effect of chlorination conditions on the pore-size distribution was noticed that gives wide possibilities to vary the pore structure of Mo 2 C derived carbons. An average pore size of carbons varied between 1 nm and 2 nm depending on chlorination temperature. The relationships were established between the pore-size distribution and the electrochemical performance of micro/mesoporous carbons. The EDL characteristics of carbon materials in a propylene carbonate solution of triethylmethylammonium tetrafluoroborate were obtained using the cyclic voltammetry at DE of 3.8 V and the constant current methods in a 3-electrode test cell. A novel test method was developed to demonstrate the power characteristics of the electrode materials. The results of this study affirmed the great potential of Mo 2 C derived carbons, whose EDL capacitance reaches $65 F cm À3 and 132 F g À1 and the 20-s discharge power density is 2.1 W cm À3 .