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The effect of [K+] on the heterogeneous rate constant for the [Fe(CN)6]3−/[Fe(CN)6]4− redox couple investigated by a.c. impedance spectroscope

✍ Scribed by S.A. Campbell; L.M. Peter

Publisher: Elsevier
Year: 1994
Tongue: English
Weight: 291 KB
Volume: 364
Category: Article
ISSN: 1572-6657
DOI: 10.1016/0022-0728(93)02922-5

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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__