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The Effect of Intermolecular Forces Upon the Vibrations of Molecules in the Crystalline State. I. The Out-of-Plane Bending of the Carbonate Ion in Aragonite Minerals

โœ Scribed by Decius, J. C.; Malan, O. G.; Thompson, H. W.


Book ID
120144165
Publisher
The Royal Society
Year
1963
Tongue
English
Weight
504 KB
Volume
275
Category
Article
ISSN
0962-8444

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Exact treatment of the vibrational isoto
โœ Tomislav P. ลฝivkoviฤ‡ ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 413 KB

Mathematical formalism of the Low Rank Perturbation (LRP) method can be applied to analyze vibrational isotope effect of arbitrary (non-planar) molecules. In LRP this effect is treated within the harmonic approximation and under assumption that force field does not change due to isotopic substitutio