The effect of incomplete mixing on homogeneous reactions
โ Scribed by P.V. Danckwerts
- Publisher
- Elsevier Science
- Year
- 1958
- Tongue
- English
- Weight
- 967 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0009-2509
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โฆ Synopsis
R&3um6-La vitesse dune reaction homogene depend du nombre de fois que les mol&mles en reaction e&rent en collision. Si le mehmge de reaction est compos6 de deuz courente entrant dans un r&xcteur 8 regime continu, ou bien de parties d'un seul coumnt qui different quant 8 leur temps de residence dens le r6acteur. la vitesse moyenne de reaction depend en g6n6ral du degre de melange des mol6cules. Elle ne se l&se g6n6ralement pas predire simplement 8 la base de la distribution des temps de residence. L'auteur discute la conception " melange B l'echelle moMculaii ", qu'il d&nit quantit&ivement, et il montre comment il peut Btre mesure. Quelques exemples d'importance pratique sent dorm& 8, titre d'ihustration. Le probleme d'un traitement g6n6ralisA des vitesses de reactions homogenes pour le CSB de melanges imparfaits est discute d'une man&e tentative. Zueammenfassung-Die Geschwindigkeit einer homogenen Reaktion wird von der Zahl der ZusammenstCsse zwischen den Molekeln der Reaktionsteilnehmer bedingt. Besteht des Reektionsgemisch aus zwei Stromen, die in einen kontinuierlichen Reaktor eintreten, oder aus friiheren und spiiteren Teilen eines einzigen Stromes, so wird die durchschnittliche Reaktionsgeschwindigkeit im allgemeinen von der Durchmischung der Molekeln bedingt. Sie l&sst sich im allgemeinen nicht einfach aus der Verteihmg der Verweilzeiten vorhers8gen. Der Begriff der ,, Durchmischung in molekularen Dimensionen " wird besprochen sowie quantitativ definiert, und es wird gezeigt, wie sie gemessen werden ksnn. Einige fur die Praxis wichtige Beispiele werden gegeben. Die Frage einer verallgemeinerten Behandlung der Geschwiudigkeiten homogener Reaktionen bei unvollst&udiger Mischung wird erorbrt. Summary-The rate of a homogeneous re8ction depends on rate of encounter between reactant molecules. When the reaction mixture consist8 of two reactant Streams flowing into a continuous reactor, or of earlier and later pasts of 8 single stream, the average rate of reaction is in general dependent on the degree of mixing on the molecular scale. It cannot generally be predicted simply from the distribution of residence times. The author analyses the concept of " mixing on the molecular scale ", gives it a quantitative definition, 8nd shows how it can be measured. Some illustrations of pm&ice1 interest are given. The problem of a generalised treatment of imperfectly mixed homogeneous reactors is tentatively discussed. ONE OF the problems involved in designing con-enable one to calculate the output of the reactor, tinuous-flow reactors from ilrst principles is that of since the chance of a molecule reacting then taking into account
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