The Effect of Hyperconjugation on the Geminal Spin-Spin Coupling Constant
β Scribed by Barfield, Michael.; Grant, David M.
- Book ID
- 126486540
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 796 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In this work it was sought to explore the versatility of geminal spin-spin coupling constants, 2 J XY SSCCs, as probes for stereochemical studies. A set of compounds, where their experimental 2 J XY SSCCs through the X-C-Y molecular fragment are predicted to be sensitive to hyperconjugative interact
It is shown that the spin-orbit coupling constant, f, far a series of 3d transition metal ions may be rtkfzctoriIy evaluated using approximate double-zeta SCF functions. The radial distance dependence of [ has been calculated, and the results indicate that the reduction of 4 below the free-ion value