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The effect of halogens on the rate of absorption of carbon dioxide

✍ Scribed by A. Tavares da Silva; P.V. Danckwerts

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
655 KB
Volume
28
Category
Article
ISSN
0009-2509

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✦ Synopsis

The presence of small amounts of chlorine or bromine greatly accelerates the rate of absorption of CO, in aqueous buffer solutions. This is because the halogens are hydrolysed to OCIor OBr-, which are powerful catalysts for the reaction between CO2 and water. An approximate mathematical analysis is given, and agrees reasonably with the observations.

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Comments on the effect of carbonic anhyd
Comments on the effect of carbonic anhydrase on carbon dioxide absorption
✍ ErdonαΈ‘an Alper πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 224 KB

values of the curves m Fig 2 as Ki\_Css/H + 0 These asymptotes are mdicated tn the figure The effect of non-bear adsorptton on the second moment is noted to be large for higher values of KLCJH Also the effect increases as the rate constants (crL and y,,) decrease In principle, plots such as Fig 2 co