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The effect of grafted TMPM on the radiation resistance of polypropylene

โœ Scribed by Huiliang Wang; Wenxiu Chen


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
174 KB
Volume
74
Category
Article
ISSN
0021-8995

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โœฆ Synopsis


The โฅ-radiation-induced graft copolymerization of 2,2,6,6-tetramethyl-4piperidinyl methacrylate (TMPM) onto polypropylene (PP) was investigated using a simultaneous-irradiation technique. The effects of solvents, atmospheres, dose, and monomer concentration on the percent of grafting were studied. The grafted TMPM showed better thermal stability, solvent extraction resistance, and compatibility with PP than monomeric TMPM or polymeric PTMPM. The stabilizing effectiveness of grafted TMPM on the radiation resistance of PP was found to be better than that of monomeric TMPM. The combination of grafted TMPM and low molecular weight hindered amine light stabilizers showed higher stabilizing effectiveness.


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