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The effect of fluorination in trimethylamine: gas-phase structures of CF3N(CH3)2 and (CF3)2NCH3

✍ Scribed by Anding Jin; Xiao-Lei Zhu; Robert L. Kirchmeier; Jean'ne M. Shreeve; Nimesh R. Patel; Heinz Oberhammer

Book ID: 107807158
Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 444 KB
Volume: 323
Category: Article
ISSN: 0022-2860
DOI: 10.1016/0022-2860(94)08308-8

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## Abstract Rate constant ratios, __k__~d~/__k__~c~ for the disproportionation/combination reaction have been measured as 0.07 ± 0.02 when an H is removed from the CH~2~ position of the CF~3~CH~2~CHCH~3~ radical and as 0.24 ± 0.03 when the H is removed from the CH~3~ position in the reaction with t