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The Effect of Film Thickness on the Suitability of Titanium Oxynitride (TiNxOy, x + y = 1) Films as Heat Mirrors – Formed by the Atmospheric Pressure CVD of TiCl4 and NH3

✍ Scribed by G. Hyett; R. Binions; I. P. Parkin


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
312 KB
Volume
13
Category
Article
ISSN
0948-1907

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✦ Synopsis


Abstract

Films of titanium oxynitride are assessed for their potential as heat mirror coatings on window glass, as a function of the film thickness. The coatings are deposited from the atmospheric pressure (AP) chemical vapor reaction of TiCl~4~ and ammonia. The heat mirror properties are evaluated using transmission and reflection spectroscopy. The composition of the samples is determined by X‐ray photoelectron spectroscopy (XPS), and the thickness of the films by scanning electron microscopy (SEM). These results suggest that an effective heat mirror can be formed by a 100 nm thick coating of titanium oxynitride, which has a transmission of 49 % in the visible (610 nm), and a reflection of 46 % in the near infrared (1320 nm).