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The effect of experimental parameters on the rate and mechanism of oxidation of methanol at a platinum anode in aqueous acid

✍ Scribed by D. Pletcher; V. Solis

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
547 KB
Volume
27
Category
Article
ISSN
0013-4686

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Evidence for the rate determining step a
Evidence for the rate determining step at the solutionβ€”oxide film interface in the anodic growth of thin oxide films at platinum and nickel electrodes in aqueous solutions
✍ A. Damjanovic; L-S.R. Yeh; J.F. Wolf πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 261 KB

The rates of growth of anodic oxide films at PI m acid and alkahna solutions and Ni III alkaline solutibns are compared. In acid solutions, the rates are pH independent. In alkaline solutions. they are affected by pH. The exchange current densities, i,, in alkaline solutions increase one decade as p