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The effect of excess volume on molecular mobility and on the mode of failure of glassy poly(ethylene terephthalate)

✍ Scribed by Mininni, R. M.; Moore, R. S.; Flick, J. R.; Petrie, S. E. B.

Book ID
121338406
Publisher
Taylor and Francis Group
Year
1973
Tongue
English
Weight
737 KB
Volume
8
Category
Article
ISSN
0022-2348

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## Abstract The effect of pressure on the crystallization of poly(ethylene terephthalate) (PET) was studied. The Instron capillary rheometer was adapted as a high‐pressure/high‐temperature dilatometer to carry on experiments up to 40,000 psi. Isothermal measurements of PET melt density were made wi

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## Abstract Previous investigators have indicated that stabilizers will block the transesterification catalyst in the preparation of PET by the DMT process. This was not the case when triphenyl phosphate (TPP) or Irganox 1010 was used as the stabilizer and manganous acetate as the catalyst. Stabili