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the effect of electrode orientation upon the anodic behaviour of the vitreous carbon-sodium polysulphide interphase at 350°C

✍ Scribed by R.D. Armstrong; M. Reid

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 99 KB
Volume: 21
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(76)85095-5

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✦ Synopsis

Upon recharging

a sodimn-sulphur battery, the melt composition changes from approxfmate-

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Alternating current impedance measuremen

Alternating current impedance measurements of the vitreous carbon/sodium polysulphide interphase at 350°C

✍ R.D. Armstrong; T. Dickinson; M. Reid 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 639 KB

Ar impedance measurements have been made at the vitreous carbon-sodium polysulphide (liquid) interphase at a temperature of 350°C. Molten Na2S3 and Na2S5 were employed. The impedance data confirm that the reaction is purely diffusion-controlled at relatively low overpotentials and that a film IS pre