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The effect of diluents on the ionic interactions in sulfonated polystyrene ionomers

✍ Scribed by J. J. Fitzgerald; Daesik Kim; R. A. Weiss

Publisher
Wiley (John Wiley & Sons)
Year
1986
Tongue
English
Weight
369 KB
Volume
24
Category
Article
ISSN
0887-6258

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Polystyrenes containing up to about 20 mol % sulfonic acid are reproducibly and readily prepared by the sulfonation of polystyrene at 50Β°C with acetyl sulfate in 1,2-dichloroethane solution. The metal salts of sulfonated polystyrene possess extremely high melt viscosities and are soluble in single s

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## Abstract The effect of polar and nonpolar low molar mass diluents on the microstructure of lightly sulfonated polystyrene (SPS) ionomers was studied using electron spin resonance spectroscopy, small‐angle x‐ray scattering, and dynamic mechanical analysis. Nonpolar diluents primarily affected the